Optimisation of radiolysis of Reactive Red 120 dye in aqueous solution using ionising (60)Co gamma radiation by response surface methodology

In recent years, employing radiation technology is gaining great interest in degradation of industrial effluents. In this work the possibility of using gamma irradiation to degrade Reactive Red 120 (C.I.292775) was explored. The effects of pH, dose of gamma irradiation and concentration of dye were...

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Veröffentlicht in:Water science and technology : a journal of the International Association on Water Pollution Research. - 1986. - 73(2016), 12 vom: 01., Seite 3041-8
1. Verfasser: Padmanaban, V C (VerfasserIn)
Weitere Verfasser: Giri Nandagopal, M S, Achary, Anant, Vasudevan, V N, Selvaraju, N
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2016
Zugriff auf das übergeordnete Werk:Water science and technology : a journal of the International Association on Water Pollution Research
Schlagworte:Journal Article Cobalt Radioisotopes Coloring Agents Triazines Water Pollutants, Chemical reactive red 120 dye 61951-82-4
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520 |a In recent years, employing radiation technology is gaining great interest in degradation of industrial effluents. In this work the possibility of using gamma irradiation to degrade Reactive Red 120 (C.I.292775) was explored. The effects of pH, dose of gamma irradiation and concentration of dye were examined and their interaction were also established based on their response. For the analysis and optimisation of variables, three factor three level Box-Wilson face centred central composite design (CCF) was used. Analysis of variance with R(2) = 0.9988, adjusted R(2) = 0.9981 and the adequate precision value of 122.303 indicates that the CCF model can be used. The coefficient of variation (0.54%) indicates the reliability of the model. The dose of gamma irradiation (kGy) and the concentration of dye (mg/L) showed significant effects on the degradation of RR 120, while a difference of 6 to 10% degradation was observed in extending the pH towards the acid or alkali range from pH 7.00. The maximum concentration of dye degraded was observed as 347.509 mg/L at initial pH: 7.0, dose of gamma irradiation: 5.94 kGy and initial concentration of dye: 500 mg/L. This predicted value was found to be in agreement with the experimental value on the optimised conditions 
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650 7 |a Cobalt Radioisotopes  |2 NLM 
650 7 |a Coloring Agents  |2 NLM 
650 7 |a Triazines  |2 NLM 
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650 7 |a reactive red 120 dye  |2 NLM 
650 7 |a 61951-82-4  |2 NLM 
700 1 |a Giri Nandagopal, M S  |e verfasserin  |4 aut 
700 1 |a Achary, Anant  |e verfasserin  |4 aut 
700 1 |a Vasudevan, V N  |e verfasserin  |4 aut 
700 1 |a Selvaraju, N  |e verfasserin  |4 aut 
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