Ambient-Temperature Synthesis of 2-Phosphathioethynolate, PCS-, and the Ligand Properties of ECX- (E = N, P; X = O, S)
A synthesis of the 2-phosphathioethynolate anion, PCS-, under ambient conditions is reported. The coordination chemistry of PCO-, PCS- and their nitrogen-containing congeners is also explored. Photolysis of a solution of W(CO)6 in the presence of PCO- [or a simple ligand displacement reaction using...
| Veröffentlicht in: | European journal of inorganic chemistry. - 1998. - 2016(2016), 5 vom: 01. Feb., Seite 639-648 |
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| 1. Verfasser: | |
| Weitere Verfasser: | , , |
| Format: | Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2016
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| Zugriff auf das übergeordnete Werk: | European journal of inorganic chemistry |
| Schlagworte: | Journal Article Coordination modes Cyanates Ligand effects P ligands Thiocyanates |