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231224s2016 xx |||||o 00| ||eng c |
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|a 10.2166/wst.2016.024
|2 doi
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|a pubmed24n0866.xml
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|a (DE-627)NLM259794295
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|a (NLM)27120640
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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|a Mungondori, Henry H
|e verfasserin
|4 aut
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|a Removal of Pb(2+) and Fe(3+) from water using N-TiO2 blended copolymer grafted asymmetric membranes
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|c 2016
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Completed 22.08.2016
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|a Date Revised 02.12.2018
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|a published: Print
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|a Citation Status MEDLINE
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|a The aim of this study was to evaluate the photo-catalytic properties of nitrogen-doped titanium dioxide nano-particles supported on polymer membranes in the photo-reduction of Fe(3+) and Pb(2+) from synthetic wastewater. The morphology of the prepared N-TiO2 nanoparticles was evaluated using transmission electron microscopy. Successful grafting of methacrylic acid side chains onto poly(vinylidene difluoride) (PVDF) backbone was confirmed by Fourier-transform infrared spectroscopy. The photo-catalytic asymmetric membranes were prepared through the dry-wet phase inversion technique. The asymmetric morphology was evaluated using scanning electron microscopy. The highest Fe(3+) photo-reduction efficiency (76.2%) was achieved in 6 hours using 1% N-TiO2-PMAA-g-PVDF/PAN (PMAA: poly(methacrylic acid); PAN: poly(acrylonitrile)) asymmetric membrane under solar irradiation. Increasing the photo-catalyst loading to 3% was found to negatively impact the photo-reduction of Fe(3+). Very high photo-reduction efficiencies were observed in the photo-reduction of Pb(2+) using 1% N-TiO2-PAN, 1% N-TiO2-PMAA-g-PVDF/PAN and 1% N-TiO2-PVDF membranes (90.5%, 88.9% and 86.9%, respectively) under similar conditions. Increasing the photo-catalyst loading to 3% N-TiO2 was observed to slightly increase the photo-reduction efficiency in the removal of Pb(2+) unlike in the case of Fe(3+). The best support material for the N-TiO2 photo-catalyst was PMAA-g-PVDF/PAN
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a Membranes, Artificial
|2 NLM
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|a Polymers
|2 NLM
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|a Water Pollutants, Chemical
|2 NLM
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|a Water
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|a 059QF0KO0R
|2 NLM
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|a titanium dioxide
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|a Lead
|2 NLM
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|a 2P299V784P
|2 NLM
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|a Titanium
|2 NLM
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|a D1JT611TNE
|2 NLM
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|a Iron
|2 NLM
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|a E1UOL152H7
|2 NLM
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|a Acrylonitrile
|2 NLM
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|a MP1U0D42PE
|2 NLM
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|a Nitrogen
|2 NLM
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|a N762921K75
|2 NLM
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|a Tichagwa, Lilian
|e verfasserin
|4 aut
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|a Katwire, David M
|e verfasserin
|4 aut
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|i Enthalten in
|t Water science and technology : a journal of the International Association on Water Pollution Research
|d 1986
|g 73(2016), 8 vom: 23., Seite 1855-64
|w (DE-627)NLM098149431
|x 0273-1223
|7 nnns
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|g volume:73
|g year:2016
|g number:8
|g day:23
|g pages:1855-64
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|u http://dx.doi.org/10.2166/wst.2016.024
|3 Volltext
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|d 73
|j 2016
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|b 23
|h 1855-64
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