|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM259124583 |
| 003 |
DE-627 |
| 005 |
20231224190516.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231224s2016 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1021/acs.langmuir.6b00243
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n0863.xml
|
| 035 |
|
|
|a (DE-627)NLM259124583
|
| 035 |
|
|
|a (NLM)27049640
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Williams, Thomas L
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Contributions of Phenoxazone-Based Pigments to the Structure and Function of Nanostructured Granules in Squid Chromatophores
|
| 264 |
|
1 |
|c 2016
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Completed 23.06.2017
|
| 500 |
|
|
|a Date Revised 23.06.2017
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status MEDLINE
|
| 520 |
|
|
|a Understanding the structure-function relationships of pigment-based nanostructures can provide insight into the molecular mechanisms behind biological signaling, camouflage, or communication experienced in many species. In squid Doryteuthis pealeii, combinations of phenoxazone-based pigments are identified as the source of visible color within the nanostructured granules that populate dermal chromatophore organs. In the absence of the pigments, granules experience a reduction in diameter with the loss of visible color, suggesting important structural and functional features. Energy gaps are estimated from electronic absorption spectra, revealing highest occupied molecular orbital (HOMO)-lowest unoccupied molecular orbital (LUMO) energies that are dependent upon the varying carboxylated states of the pigment. These results implicate a hierarchical mechanism for the bulk coloration in cephalopods originating from the molecular components confined within in the nanostructured granules of chromatophore organs
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a Research Support, Non-U.S. Gov't
|
| 650 |
|
4 |
|a Research Support, U.S. Gov't, Non-P.H.S.
|
| 650 |
|
7 |
|a Oxazines
|2 NLM
|
| 650 |
|
7 |
|a Pigments, Biological
|2 NLM
|
| 650 |
|
7 |
|a Xanthenes
|2 NLM
|
| 650 |
|
7 |
|a xanthommatin
|2 NLM
|
| 650 |
|
7 |
|a 521-58-4
|2 NLM
|
| 700 |
1 |
|
|a DiBona, Christopher W
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Dinneen, Sean R
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Labadie, Stephanie F Jones
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Chu, Feixia
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Deravi, Leila F
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1999
|g 32(2016), 15 vom: 19. Apr., Seite 3754-9
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
|
| 773 |
1 |
8 |
|g volume:32
|g year:2016
|g number:15
|g day:19
|g month:04
|g pages:3754-9
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1021/acs.langmuir.6b00243
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_22
|
| 912 |
|
|
|a GBV_ILN_350
|
| 912 |
|
|
|a GBV_ILN_721
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 32
|j 2016
|e 15
|b 19
|c 04
|h 3754-9
|