Rheological Properties of Viscoelastic Drops on Superamphiphobic Substrates

The rheological properties of microliter sized drops of polymer solutions were investigated using measurements of their mechanical vibrational response. Drops were suspended on superamphiphobic substrates and vibrated by the application of a short mechanical impulse. Surface vibrations were monitore...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 32(2016), 16 vom: 26. Apr., Seite 4071-6
1. Verfasser: Harrold, Victoria C (VerfasserIn)
Weitere Verfasser: Paven, Maxime, Vollmer, Doris, Sharp, James S
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2016
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't
Beschreibung
Zusammenfassung:The rheological properties of microliter sized drops of polymer solutions were investigated using measurements of their mechanical vibrational response. Drops were suspended on superamphiphobic substrates and vibrated by the application of a short mechanical impulse. Surface vibrations were monitored by refracting laser light through the drops and focusing the refracted light onto the surface of a photodiode. Time dependent variations in the photodiode output were Fourier transformed to obtain the frequency and spectral width of the mechanical resonances of the drops. These quantities were related to the frequency dependent shear storage and loss moduli (G' and G″, respectively) using a simple theoretical model. The resulting rheological properties were found to be in agreement with microrheology measurements of the same solutions. Drop vibration therefore provides a fast and accurate method of quantifying the rheological properties of single drops
Beschreibung:Date Completed 18.05.2018
Date Revised 18.05.2018
published: Print-Electronic
Citation Status PubMed-not-MEDLINE
ISSN:1520-5827
DOI:10.1021/acs.langmuir.6b00779