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231224s2016 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.6b00427
|2 doi
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|a eng
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|a Sen, Rickdeb
|e verfasserin
|4 aut
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|a Use of Ambient Ionization High-Resolution Mass Spectrometry for the Kinetic Analysis of Organic Surface Reactions
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|c 2016
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|a Text
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|a ƒaComputermedien
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|a Date Completed 15.08.2016
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|a Date Revised 12.04.2016
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a In contrast to homogeneous systems, studying the kinetics of organic reactions on solid surfaces remains a difficult task due to the limited availability of appropriate analysis techniques that are general, high-throughput, and capable of offering quantitative, structural surface information. Here, we demonstrate how direct analysis in real time mass spectrometry (DART-MS) complies with above considerations and can be used for determining interfacial kinetic parameters. The presented approach is based on the use of a MS tag that--in principle--allows application to other reactions. To show the potential of DART-MS, we selected the widely applied strain-promoted alkyne-azide cycloaddition (SPAAC) as a model reaction to elucidate the effects of the nanoenvironment on the interfacial reaction rate
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a Escorihuela, Jorge
|e verfasserin
|4 aut
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|a Smulders, Maarten M J
|e verfasserin
|4 aut
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1 |
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|a Zuilhof, Han
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 32(2016), 14 vom: 12. Apr., Seite 3412-9
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|x 1520-5827
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|g volume:32
|g year:2016
|g number:14
|g day:12
|g month:04
|g pages:3412-9
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