Chiral-Linkage-Induced Hierarchical Ordering of Colloidal Achiral Nanotubes in their Thixotropic Gel

Macroscopic continuous hierarchical ordering of achiral nanotube "imogolite" was achieved by thixotropic gelation of imogolite with chiral hydroxy acid and their flow-orienting/subsequent standing for uniaxial alignments of imogolite. The chirality change of the hydroxy acids resulted in a...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1985. - 32(2016), 15 vom: 19. Apr., Seite 3665-9
1. Verfasser: Shikinaka, Kazuhiro (VerfasserIn)
Weitere Verfasser: Kikuchi, Hiroto, Maki, Tei, Shigehara, Kiyotaka, Masunaga, Hiroyasu, Sato, Hisako
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2016
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't
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520 |a Macroscopic continuous hierarchical ordering of achiral nanotube "imogolite" was achieved by thixotropic gelation of imogolite with chiral hydroxy acid and their flow-orienting/subsequent standing for uniaxial alignments of imogolite. The chirality change of the hydroxy acids resulted in an inversion of the helical ordering. The study presented here first exhibits the millimeter-scale supramolecular chirality induced by angstrom-scale molecular handedness in the architecture of nanotubes 
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700 1 |a Maki, Tei  |e verfasserin  |4 aut 
700 1 |a Shigehara, Kiyotaka  |e verfasserin  |4 aut 
700 1 |a Masunaga, Hiroyasu  |e verfasserin  |4 aut 
700 1 |a Sato, Hisako  |e verfasserin  |4 aut 
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