A Significantly Twisted Spirocyclic Phosphine Oxide as a Universal Host for High-Efficiency Full-Color Thermally Activated Delayed Fluorescence Diodes
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Publié dans: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 28(2016), 16 vom: 21. Apr., Seite 3122-30 |
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Auteur principal: | |
Autres auteurs: | , , , , , , |
Format: | Article en ligne |
Langue: | English |
Publié: |
2016
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Accès à la collection: | Advanced materials (Deerfield Beach, Fla.) |
Sujets: | Journal Article Research Support, Non-U.S. Gov't full color spiro compounds thermally activated delayed fluorescence diodes twisted configuration universal host |
Résumé: | © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. A universal thermally activated delayed fluorescence (TADF) host, 4'-diphenylphosphinoylspiro[fluorene-9,9'-xanthene] (SFXSPO), is constructed with a highly distorted and asymmetric configuration and disordered molecular packing in its solid state. SFXSPO successfully endows its full-color TADF diodes with state-of-the-art performance, e.g., the record external quantum efficiency of 22.5% and 19.1% and internal quantum efficiency of ≈100% for its yellow TADF diodes and single-host full-TADF nearly-white-emitting devices, respectively |
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Description: | Date Completed 02.06.2017 Date Revised 30.09.2020 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
ISSN: | 1521-4095 |
DOI: | 10.1002/adma.201506286 |