Local reaction kinetics by imaging

In the present contribution we present an overview of our recent studies using the "kinetics by imaging" approach for CO oxidation on heterogeneous model systems. The method is based on the correlation of the PEEM image intensity with catalytic activity: scaled down to the μm-sized surface...

Ausführliche Beschreibung

Bibliographische Detailangaben
Veröffentlicht in:Surface science. - 1997. - 643(2016) vom: 01. Jan., Seite 52-58
1. Verfasser: Suchorski, Yuri (VerfasserIn)
Weitere Verfasser: Rupprechter, Günther
Format: Aufsatz
Sprache:English
Veröffentlicht: 2016
Zugriff auf das übergeordnete Werk:Surface science
Schlagworte:Journal Article CO oxidation Catalysis Catalytic ignition Palladium Photoemission electron microscopy Platinum
LEADER 01000caa a22002652 4500
001 NLM257368787
003 DE-627
005 20250219170844.0
007 tu
008 231224s2016 xx ||||| 00| ||eng c
028 5 2 |a pubmed25n0857.xml 
035 |a (DE-627)NLM257368787 
035 |a (NLM)26865736 
040 |a DE-627  |b ger  |c DE-627  |e rakwb 
041 |a eng 
100 1 |a Suchorski, Yuri  |e verfasserin  |4 aut 
245 1 0 |a Local reaction kinetics by imaging 
264 1 |c 2016 
336 |a Text  |b txt  |2 rdacontent 
337 |a ohne Hilfsmittel zu benutzen  |b n  |2 rdamedia 
338 |a Band  |b nc  |2 rdacarrier 
500 |a Date Revised 23.05.2024 
500 |a published: Print 
500 |a Citation Status PubMed-not-MEDLINE 
520 |a In the present contribution we present an overview of our recent studies using the "kinetics by imaging" approach for CO oxidation on heterogeneous model systems. The method is based on the correlation of the PEEM image intensity with catalytic activity: scaled down to the μm-sized surface regions, such correlation allows simultaneous local kinetic measurements on differently oriented individual domains of a polycrystalline metal-foil, including the construction of local kinetic phase diagrams. This allows spatially- and component-resolved kinetic studies and, e.g., a direct comparison of inherent catalytic properties of Pt(hkl)- and Pd(hkl)-domains or supported μm-sized Pd-powder agglomerates, studies of the local catalytic ignition and the role of defects and grain boundaries in the local reaction kinetics 
650 4 |a Journal Article 
650 4 |a CO oxidation 
650 4 |a Catalysis 
650 4 |a Catalytic ignition 
650 4 |a Palladium 
650 4 |a Photoemission electron microscopy 
650 4 |a Platinum 
700 1 |a Rupprechter, Günther  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Surface science  |d 1997  |g 643(2016) vom: 01. Jan., Seite 52-58  |w (DE-627)NLM098126490  |x 0039-6028  |7 nnns 
773 1 8 |g volume:643  |g year:2016  |g day:01  |g month:01  |g pages:52-58 
912 |a GBV_USEFLAG_A 
912 |a SYSFLAG_A 
912 |a GBV_NLM 
912 |a GBV_ILN_350 
951 |a AR 
952 |d 643  |j 2016  |b 01  |c 01  |h 52-58