Long-Range Proton Conduction across Free-Standing Serum Albumin Mats
© 2016 The Authors. Published by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Veröffentlicht in: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 28(2016), 14 vom: 13. Apr., Seite 2692-8 |
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1. Verfasser: | |
Weitere Verfasser: | , , , |
Format: | Online-Aufsatz |
Sprache: | English |
Veröffentlicht: |
2016
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Zugriff auf das übergeordnete Werk: | Advanced materials (Deerfield Beach, Fla.) |
Schlagworte: | Journal Article Research Support, Non-U.S. Gov't current-voltage hopping mechanism impedance spectroscopy protein films proton transfer Protons Serum Albumin, Bovine 27432CM55Q |
Zusammenfassung: | © 2016 The Authors. Published by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Free-standing serum-albumin mats can transport protons over millimetre length-scales. The results of photoinduced proton transfer and voltage-driven proton-conductivity measurements, together with temperature-dependent and isotope-effect studies, suggest that oxo-amino-acids of the protein serum albumin play a major role in the translocation of protons via an "over-the-barrier" hopping mechanism. The use of proton-conducting protein mats opens new possibilities for bioelectronic interfaces |
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Beschreibung: | Date Completed 21.12.2016 Date Revised 29.01.2022 published: Print-Electronic Citation Status MEDLINE |
ISSN: | 1521-4095 |
DOI: | 10.1002/adma.201505337 |