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231224s2016 xx |||||o 00| ||eng c |
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7 |
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|a 10.1021/acs.langmuir.5b04278
|2 doi
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|a pubmed24n0856.xml
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|a eng
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|a Manivannan, Shanmugam
|e verfasserin
|4 aut
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|a In Situ Growth of Prussian Blue Nanostructures at Reduced Graphene Oxide as a Modified Platinum Electrode for Synergistic Methanol Oxidation
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|c 2016
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Completed 21.06.2016
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|a Date Revised 23.02.2016
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Herein, we report a facile synthetic strategy for the in situ growth of Prussian blue nanostructures (PB NSs) at the amine-functionalized silicate sol-gel matrix (TPDT)-RGO composite via the electrostatic interaction. Subsequently, Pt nanostructures are electrodeposited onto the preformed ITO/TPDT-RGO-PB electrode to prepare the RGO/PB/Pt catalyst. The significance of the present method is that the PB NSs are in situ grown by interconnecting the RGO layers, leading to 3D cage-like porous nanostructure. The modified electrodes are characterized by FESEM, EDAX, XRD, XPS, and electrochemical techniques. The RGO/PB/Pt catalyst exhibits synergistic electrocatalytic activity and high stability toward methanol oxidation. The porous nature of the TPDT and PB and unique electron-transfer mediating behavior of PB integrated with RGO in the presence of Pt nanostructures facilitated synergistic electrocatalytic activity for methanol oxidation
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a Kang, Inhak
|e verfasserin
|4 aut
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|a Kim, Kyuwon
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 32(2016), 7 vom: 23. Feb., Seite 1890-8
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
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|g volume:32
|g year:2016
|g number:7
|g day:23
|g month:02
|g pages:1890-8
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|u http://dx.doi.org/10.1021/acs.langmuir.5b04278
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