Hydrogel Inverse Replicas of Breath Figures Exhibit Superoleophobicity Due to Patterned Surface Roughness

The wetting behavior of a surface depends on both its surface chemistry and the characteristics of surface morphology and topography. Adding structure to a flat hydrophobic or oleophobic surface increases the effective contact angle and thus the hydrophobicity or oleophobicity of the surface, as exe...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 32(2016), 4 vom: 02. Feb., Seite 1009-17
1. Verfasser: Arora, Jaspreet Singh (VerfasserIn)
Weitere Verfasser: Cremaldi, Joseph C, Holleran, Mary Kathleen, Ponnusamy, Thiruselvam, He, Jibao, Pesika, Noshir S, John, Vijay T
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2016
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, U.S. Gov't, Non-P.H.S.
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520 |a The wetting behavior of a surface depends on both its surface chemistry and the characteristics of surface morphology and topography. Adding structure to a flat hydrophobic or oleophobic surface increases the effective contact angle and thus the hydrophobicity or oleophobicity of the surface, as exemplified by the lotus leaf analogy. We describe a simple strategy to introduce micropatterned roughness on surfaces of soft materials, utilizing the template of hexagonally packed pores of breath figures as molds. The generated inverse replicas represent micron scale patterned beadlike protrusions on hydrogel surfaces. This added roughness imparts superoleophobic properties (contact angle of the order of 150° and greater) to an inherently oleophobic flat hydrogel surface, when submerged. The introduced pattern on the hydrogel surface changes morphology as it swells in water to resemble morphologies remarkably analogous to the compound eye. Analysis of the wetting behavior using the Cassie-Baxter approximation leads to estimation of the contact angle in the superoleophobic regime and in agreement with the experimental value 
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650 4 |a Research Support, U.S. Gov't, Non-P.H.S. 
700 1 |a Cremaldi, Joseph C  |e verfasserin  |4 aut 
700 1 |a Holleran, Mary Kathleen  |e verfasserin  |4 aut 
700 1 |a Ponnusamy, Thiruselvam  |e verfasserin  |4 aut 
700 1 |a He, Jibao  |e verfasserin  |4 aut 
700 1 |a Pesika, Noshir S  |e verfasserin  |4 aut 
700 1 |a John, Vijay T  |e verfasserin  |4 aut 
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