Consequences of Tacticity on the Growth and Permeability of Hyperthin Polyelectrolyte Multilayers
A series of polyanions and polycations have been synthesized from atactic, syndiotactic, and isotactic forms of poly(methyl methacrylate) and used to construct polyelectrolyte multilayers (PEMs). Polymer tacticity has been found to have a large influence on film growth but only a slight effect on H2...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 32(2016), 2 vom: 19. Jan., Seite 375-9 |
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| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2016
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article Research Support, U.S. Gov't, Non-P.H.S. |
| Zusammenfassung: | A series of polyanions and polycations have been synthesized from atactic, syndiotactic, and isotactic forms of poly(methyl methacrylate) and used to construct polyelectrolyte multilayers (PEMs). Polymer tacticity has been found to have a large influence on film growth but only a slight effect on H2/N2 permeation selectivities and no significant influence on CO2/N2 permeation selectivities. The permeances of H2, CO2, and N2 across those PEMs exhibiting the highest H2/N2 selectivities were found to vary by as much as factors of 3, 6, and 5, respectively, depending on the tacticities employed. A simple model that accounts for the strong dependency of film growth on tacticity is presented |
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| Beschreibung: | Date Completed 26.05.2016 Date Revised 19.01.2016 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/acs.langmuir.5b04241 |