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231224s2016 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.5b03913
|2 doi
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|a pubmed24n0853.xml
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|a eng
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|a Hegemann, Dirk
|e verfasserin
|4 aut
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|a Suppression of Hydrophobic Recovery by Plasma Polymer Films with Vertical Chemical Gradients
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|c 2016
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Completed 26.05.2016
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|a Date Revised 26.01.2016
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Vertical chemical gradients extending over a few nanometers were explored. The gradients are based on plasma-polymerized oxygen-containing ethylene (ppOEt) films. Using plasma conditions with low CO2/C2H4 ratio and high energy input, cross-linked films were deposited as base layer, while increasing CO2 and lowering energy input resulted in less cross-linked yet highly functional films as applied as top layer. Aging studies indicate that, in particular, for very thin gradient structures, the cross-linked subsurface zone effectively hinders reorientation of the surface functional groups, thus restricting hydrophobic recovery and oxidation effects
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a Lorusso, Emanuela
|e verfasserin
|4 aut
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|a Butron-Garcia, Maria-Isabel
|e verfasserin
|4 aut
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|a Blanchard, Noémi E
|e verfasserin
|4 aut
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|a Rupper, Patrick
|e verfasserin
|4 aut
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|a Favia, Pietro
|e verfasserin
|4 aut
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|a Heuberger, Manfred
|e verfasserin
|4 aut
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|a Vandenbossche, Marianne
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1999
|g 32(2016), 3 vom: 26. Jan., Seite 651-4
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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|g volume:32
|g year:2016
|g number:3
|g day:26
|g month:01
|g pages:651-4
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|u http://dx.doi.org/10.1021/acs.langmuir.5b03913
|3 Volltext
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