Simultaneous removal of ammonium and nitrate by HDTMA-modified zeolite

In this study, surfactant (hexadecyltrimethylammonium, HDTMA) modified zeolite (clinoptilolite) (SMZ) was used for simultaneous removal of ammonium and nitrate in wastewater, and the sorption properties of SMZ were determined. Results showed that natural clinoptilolite had good affinity for ammonium...

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Publié dans:Water science and technology : a journal of the International Association on Water Pollution Research. - 1986. - 72(2015), 11 vom: 28., Seite 1931-9
Auteur principal: Tao, Quan (Auteur)
Autres auteurs: Hu, Mu, Ma, Xiaofang, Xiang, Mingli, Zhang, Tian C, Li, Chengle, Yao, Jing, Liang, Ying
Format: Article en ligne
Langue:English
Publié: 2015
Accès à la collection:Water science and technology : a journal of the International Association on Water Pollution Research
Sujets:Journal Article Ammonium Compounds Nitrates Polymethacrylic Acids Quaternary Ammonium Compounds Surface-Active Agents hexadecyltrimethylammonium polymethacrylate clinoptilolite 12173-10-3 Zeolites 1318-02-1
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520 |a In this study, surfactant (hexadecyltrimethylammonium, HDTMA) modified zeolite (clinoptilolite) (SMZ) was used for simultaneous removal of ammonium and nitrate in wastewater, and the sorption properties of SMZ were determined. Results showed that natural clinoptilolite had good affinity for ammonium, but low sorption ability for nitrate, and the ammonium sorption process was well described by the pseudo-second order kinetic model. The SMZ had a significant enhancement on nitrate sorption and could simultaneously remove ammonium and nitrate at specific conditions, with removal efficiency up to 93.6% and 81.8%, respectively. The sorption process fitted well with the Langmuir isotherm. Orthogonal experiments showed that ammonium concentration was the most important factor for ammonium sorption on SMZ. However, surfactant loading was the major factor for nitrate sorption. Meanwhile, phosphate did not interfere with nitrate removal. Semi-empirical quantum mechanics molecular simulation indicated that electrostatic attraction existed between HDTMA and nitrate. Results of this study demonstrated that SMZs may have great potential for removing cations and anions simultaneously in the aquatic environment 
650 4 |a Journal Article 
650 7 |a Ammonium Compounds  |2 NLM 
650 7 |a Nitrates  |2 NLM 
650 7 |a Polymethacrylic Acids  |2 NLM 
650 7 |a Quaternary Ammonium Compounds  |2 NLM 
650 7 |a Surface-Active Agents  |2 NLM 
650 7 |a hexadecyltrimethylammonium polymethacrylate  |2 NLM 
650 7 |a clinoptilolite  |2 NLM 
650 7 |a 12173-10-3  |2 NLM 
650 7 |a Zeolites  |2 NLM 
650 7 |a 1318-02-1  |2 NLM 
700 1 |a Hu, Mu  |e verfasserin  |4 aut 
700 1 |a Ma, Xiaofang  |e verfasserin  |4 aut 
700 1 |a Xiang, Mingli  |e verfasserin  |4 aut 
700 1 |a Zhang, Tian C  |e verfasserin  |4 aut 
700 1 |a Li, Chengle  |e verfasserin  |4 aut 
700 1 |a Yao, Jing  |e verfasserin  |4 aut 
700 1 |a Liang, Ying  |e verfasserin  |4 aut 
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