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231224s2016 xx |||||o 00| ||eng c |
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|a 10.1002/adma.201503162
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|a eng
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|a Street, Robert A
|e verfasserin
|4 aut
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|a Electronic Structure and Properties of Organic Bulk-Heterojunction Interfaces
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|c 2016
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|a Text
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|a ƒaComputermedien
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|a Date Completed 02.06.2017
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|a Date Revised 30.09.2020
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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|a The electronic structure and physical mechanisms of carrier generation and transport in the organic bulk heterojunction are reviewed. The electronic structure describes the bands and band-tail states, the band alignment at the bulk-heterojunction interface, and the overall density-of-states model. The different electronic character of excitons and mobile charge is discussed, the former being highly molecular and the latter more delocalized. Dissociation of the exciton via the charge-transfer (CT) states is attributed to weak binding of the CT state arising from charge delocalization. Carrier transport and charge collection is strongly influenced by the presence of localized band-tail states. Recombination is attributed primarily to transitions from mobile carriers to band-tail or deep trap states
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|a Journal Article
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|a bulk heterojunctions
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|a charge-transfer state
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|a electronic structure
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|a localized band tails
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|a organic semiconductors
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 28(2016), 20 vom: 18. Mai, Seite 3814-30
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|x 1521-4095
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|g year:2016
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|g day:18
|g month:05
|g pages:3814-30
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|u http://dx.doi.org/10.1002/adma.201503162
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