Lubrication Properties of Ammonium-Based Ionic Liquids Confined between Silica Surfaces Using Resonance Shear Measurements

To evaluate the friction properties of new lubrication systems, two types of ammonium-based ionic liquids (ILs), N,N-diethyl-N-methyl-N-(2-methoxyethyl) ammonium tetrafluoroborate ([DEME][BF4]) and N,N-diethyl-N-methyl-N-(2-methoxyethyl) ammonium bis(trifluoromethanesulfonyl) imide ([DEME][TFSI]), w...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 31(2015), 49 vom: 15. Dez., Seite 13265-70
1. Verfasser: Kamijo, Toshio (VerfasserIn)
Weitere Verfasser: Arafune, Hiroyuki, Morinaga, Takashi, Honma, Saika, Sato, Takaya, Hino, Masaya, Mizukami, Masashi, Kurihara, Kazue
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2015
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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245 1 0 |a Lubrication Properties of Ammonium-Based Ionic Liquids Confined between Silica Surfaces Using Resonance Shear Measurements 
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520 |a To evaluate the friction properties of new lubrication systems, two types of ammonium-based ionic liquids (ILs), N,N-diethyl-N-methyl-N-(2-methoxyethyl) ammonium tetrafluoroborate ([DEME][BF4]) and N,N-diethyl-N-methyl-N-(2-methoxyethyl) ammonium bis(trifluoromethanesulfonyl) imide ([DEME][TFSI]), were investigated by resonance shear measurements (RSM) and reciprocating type tribotests between silica (glass) surfaces. RSM revealed that an IL layer of ca. 2 nm in thickness was maintained between the silica surfaces under an applied load of 0.40 mN ∼ 1.2 mN. The relative intensity of the RMS signal indicated that the friction of the system was lower for [DEME][BF4], 0.12, than that of [DEME][TFSI], 0.18. On the other hand, the friction coefficients μk obtained from the tribotests of [DEME][BF4] were lower than that of [DEME][TFSI] for sliding velocities in the range of 5.0 × 10(-4) m s(-1) to 3.0 × 10(-2) m s(-1) under applied loads of 196-980 mN. The friction coefficients obtained by the tribotest are discussed with reference to the RSM results 
650 4 |a Journal Article 
700 1 |a Arafune, Hiroyuki  |e verfasserin  |4 aut 
700 1 |a Morinaga, Takashi  |e verfasserin  |4 aut 
700 1 |a Honma, Saika  |e verfasserin  |4 aut 
700 1 |a Sato, Takaya  |e verfasserin  |4 aut 
700 1 |a Hino, Masaya  |e verfasserin  |4 aut 
700 1 |a Mizukami, Masashi  |e verfasserin  |4 aut 
700 1 |a Kurihara, Kazue  |e verfasserin  |4 aut 
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