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231224s2015 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.5b03924
|2 doi
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|a pubmed24n0849.xml
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|a DE-627
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|e rakwb
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|a eng
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| 100 |
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|a Vonhören, Benjamin
|e verfasserin
|4 aut
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| 245 |
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|a Fast and Simple Preparation of Patterned Surfaces with Hydrophilic Polymer Brushes by Micromolding in Capillaries
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|c 2015
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Completed 16.09.2016
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|a Date Revised 02.12.2018
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a Micropatterns of hydrophilic polymer brushes were prepared by micromolding in capillaries (MIMIC). The polymers are covalently bound to the surfaces by a rapid hetero Diels-Alder reaction, constituting the first example of polymers grafted to surfaces in a defined pattern by MIMIC. The polymers [poly(acrylic acid), poly(hydroxyethyl acrylate), and poly(tetraethylene glycol acrylate) ranging in molecular weight from 1500 to 6000 g mol(-1)] were prepared with narrow dispersities via the reversible addition-fragmentation chain transfer (RAFT) process using a highly electron deficient RAFT agent that can react with surface-anchored dienes such as cyclopentadiene. We demonstrate that the anchoring method is facile to perform and highly suitable for preparing patterned surfaces that are passivated against biological impact in well-defined areas
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a Acrylates
|2 NLM
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|a Acrylic Resins
|2 NLM
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|a Polymers
|2 NLM
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|a poly(hydroxylethyl acrylate)
|2 NLM
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|a Polyethylene Glycols
|2 NLM
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|a 3WJQ0SDW1A
|2 NLM
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|a carbopol 940
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| 700 |
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|a Langer, Marcel
|e verfasserin
|4 aut
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|a Abt, Doris
|e verfasserin
|4 aut
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|a Barner-Kowollik, Christopher
|e verfasserin
|4 aut
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|a Ravoo, Bart Jan
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 31(2015), 50 vom: 22. Dez., Seite 13625-31
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|x 1520-5827
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|g volume:31
|g year:2015
|g number:50
|g day:22
|g month:12
|g pages:13625-31
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|u http://dx.doi.org/10.1021/acs.langmuir.5b03924
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