Liposome Membrane as a Platform for the L-Pro-Catalyzed Michael Addition of trans-β-Nitrostyrene and Acetone

Herein, we show that the L-proline (L-Pro)-catalyzed Michael addition of trans-β-nitrostyrene and acetone can proceed in "water" using liposome membranes and that the membrane fluidity and polarity are major controlling factors for this reaction. The highest conversion and rate constant of...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1985. - 31(2015), 47 vom: 01. Dez., Seite 12968-74
1. Verfasser: Hirose, Masanori (VerfasserIn)
Weitere Verfasser: Ishigami, Takaaki, Suga, Keishi, Umakoshi, Hiroshi
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2015
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't 1,2-dipalmitoyl-3-trimethylammonium-propane Liposomes Phosphatidylcholines Quaternary Ammonium Compounds Styrenes Acetone 1364PS73AF beta-nitrostyrene mehr... 5287E3OUAV Proline 9DLQ4CIU6V 1,2-oleoylphosphatidylcholine EDS2L3ODLV Propane T75W9911L6