A strenuous experimental journey searching for spectroscopic evidence of a bridging nickel-iron-hydride in [NiFe] hydrogenase
Direct spectroscopic evidence for a hydride bridge in the Ni-R form of [NiFe] hydrogenase has been obtained using iron-specific nuclear resonance vibrational spectroscopy (NRVS). The Ni-H-Fe wag mode at 675 cm(-1) is the first spectroscopic evidence for a bridging hydride in Ni-R as well as the firs...
Ausführliche Beschreibung
Bibliographische Detailangaben
| Veröffentlicht in: | Journal of synchrotron radiation. - 1994. - 22(2015), 6 vom: 11. Nov., Seite 1334-44
|
|---|
| 1. Verfasser: |
Wang, Hongxin
(VerfasserIn) |
|---|
| Weitere Verfasser: |
Yoda, Yoshitaka,
Ogata, Hideaki,
Tanaka, Yoshihito,
Lubitz, Wolfgang |
|---|
| Format: | Online-Aufsatz
|
|---|
| Sprache: | English |
|---|
| Veröffentlicht: |
2015
|
|---|
| Zugriff auf das übergeordnete Werk: | Journal of synchrotron radiation
|
|---|
| Schlagworte: | Journal Article
Research Support, N.I.H., Extramural
Research Support, U.S. Gov't, Non-P.H.S.
NRVS
Ni–H–Fe wag mode
Ni–R
[NiFe] hydrogenase
iron hydride
nuclear resonance vibrational spectroscopy
ultra-weak signal
mehr...
Hydrogen
7YNJ3PO35Z
nickel-iron hydrogenase
EC 1.12.-
Hydrogenase
EC 1.12.7.2 |
|---|