Adsorptive Separation of Olefin/Paraffin Mixtures with ZIF-4

The microporous zeolitic imidazolate framework ZIF-4 has been synthesized, and its ethylene/ethane and propylene/propane separation potentials have been evaluated by single-component adsorption isotherms and breakthrough experiments of the respective binary mixtures. In all experiments, a higher sel...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 31(2015), 45 vom: 17. Nov., Seite 12382-9
1. Verfasser: Hartmann, Martin (VerfasserIn)
Weitere Verfasser: Böhme, Ulrike, Hovestadt, Maximilian, Paula, Carolin
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2015
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a The microporous zeolitic imidazolate framework ZIF-4 has been synthesized, and its ethylene/ethane and propylene/propane separation potentials have been evaluated by single-component adsorption isotherms and breakthrough experiments of the respective binary mixtures. In all experiments, a higher selectivity for the paraffin is observed that is manifested by a steeper equilibrium isotherm as well as a later breakthrough in the fixed-bed adsorber experiments. Microporous adsorbents with paraffin selectivity are rare but highly interesting for cyclic adsorption processes such as pressure-swing adsorption (PSA) 
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