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231224s2015 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.5b02730
|2 doi
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|a pubmed24n0845.xml
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|a (NLM)26465964
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|a DE-627
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|e rakwb
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|a eng
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| 100 |
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|a Liu, He
|e verfasserin
|4 aut
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|a Micropatterns of [Fe-Fe]-Hydrogenase Active-Site Model Complexes Fabricated by Electro-Oxidative Lithography
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|c 2015
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Completed 14.03.2016
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|a Date Revised 27.10.2015
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a [Fe-Fe]-hydrogenase active site model complexes ([Fe(CO)3]2[(μ-SCH2)2C(CH2OH)2]) were immobilized on micropatterned n-octadecyltrichlorosilane (OTS) monolayers deposited on a Si substrate to form a microscale catalytic system. The micropatterns were generated by electro-oxidative lithography performed with a conductive TEM grid. The [Fe-Fe]-hydrogenase active-site complex molecules were selectively anchored in lithographic line areas with good coverage. Additionally, the biomimetic metal centers of the hydrogenase active-site complex molecules still maintained their catalytic activity and their redox-active properties after the immobilization process, which was proven by cyclic voltammetry
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|a Journal Article
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|a Trautwein, Ralf
|e verfasserin
|4 aut
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|a Schröter, Bernd
|e verfasserin
|4 aut
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|a Ignaszak, Anna
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Weigand, Wolfgang
|e verfasserin
|4 aut
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|a Hoeppener, Stephanie
|e verfasserin
|4 aut
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|a Schubert, Ulrich S
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 31(2015), 42 vom: 27. Okt., Seite 11748-53
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|x 1520-5827
|7 nnns
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| 773 |
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|g volume:31
|g year:2015
|g number:42
|g day:27
|g month:10
|g pages:11748-53
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|u http://dx.doi.org/10.1021/acs.langmuir.5b02730
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