Design and Synthesis of the Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material Ba₃(ZnB₅O₁₀)PO₄
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
| Publié dans: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 27(2015), 45 vom: 02. Dez., Seite 7380-5 |
|---|---|
| Auteur principal: | |
| Autres auteurs: | , , , |
| Format: | Article en ligne |
| Langue: | English |
| Publié: |
2015
|
| Accès à la collection: | Advanced materials (Deerfield Beach, Fla.) |
| Sujets: | Journal Article DFT calculations borate-phosphates deep ultraviolet nonlinear optical materials second-harmonic generation |
| Résumé: | © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. Access to the elusive deep-ultraviolet by direct second harmonic generation (SHG) enabled by a new beryllium-free zincoborate-phosphate crystal is reported. Ba3(ZnB5O10)PO4, exhibits large SHG responses at 1064 and 532 nm and a short 180 nm absorption edge. Centimeter-size crystals are grown, and quantum mechanical calculations demonstrate the key role played by ZnO4 tetrahedra in the enhanced optical responses |
|---|---|
| Description: | Date Completed 23.03.2016 Date Revised 01.10.2020 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1521-4095 |
| DOI: | 10.1002/adma.201503951 |