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231224s2015 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.5b02965
|2 doi
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|a pubmed24n0845.xml
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|a (DE-627)NLM253592569
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|a (NLM)26457573
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|a DE-627
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|e rakwb
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|a eng
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| 100 |
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|a Chen, Jian
|e verfasserin
|4 aut
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| 245 |
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|a In-Plane Intermolecular Interaction Assisted Assembly and Modified Electronic States of Metallofullerene GdC₈₂
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|c 2015
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Completed 16.09.2016
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|a Date Revised 27.10.2015
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a Orientational configuration and electronic states of GdC82 bonding to Cu(111) have been thoroughly investigated by low-temperature scanning tunneling microscopy/spectroscopy (LT-STM/S) and differential conductance mapping complemented by first-principles calculations. We clarify that individual Gd@C82 energetically adopts tilting adsorption configuration with the scanning tunneling spectroscopy (STS) states readily assigned to the C82 cage/Cu(111) hybrid states and the Gd/cage hybrid states, respectively. Moreover, upon assembling and sufficient thermal activation, Gd@C82 fullerenes are inclined to restore the energetically favored tilting orientational configuration similar to an individual one. This suggests the feasibility of high-level integration of single-Gd@C82 based moletronic device with the performances almost unchanged by two-dimensional arrangement. Furthermore, by rationalizing the inter-Gd@C82 interaction induced slight energy offset of the electronic states, we qualitatively confirm the shown electronic hybrid states as Cu(111)-, C82 cage- and Gd-dominant hybrid states, respectively
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a Fullerenes
|2 NLM
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|a Gadolinium
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|a AU0V1LM3JT
|2 NLM
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| 700 |
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|a Qin, Zhihui
|e verfasserin
|4 aut
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|a Pan, Jinbo
|e verfasserin
|4 aut
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|a Huang, Min
|e verfasserin
|4 aut
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|a Du, Shixuan
|e verfasserin
|4 aut
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|a Cao, Gengyu
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 31(2015), 42 vom: 27. Okt., Seite 11438-42
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
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|g volume:31
|g year:2015
|g number:42
|g day:27
|g month:10
|g pages:11438-42
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|u http://dx.doi.org/10.1021/acs.langmuir.5b02965
|3 Volltext
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