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231224s2015 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.5b02442
|2 doi
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|a DE-627
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|a eng
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|a Tanaka, Daisuke
|e verfasserin
|4 aut
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|a Alternation of Side-Chain Mesogen Orientation Caused by the Backbone Structure in Liquid-Crystalline Polymer Thin Films
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|c 2015
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Completed 14.03.2016
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|a Date Revised 27.10.2015
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a In side-chain-type liquid-crystalline (LC) polymers, the main chain rigidity significantly affects the LC structure and properties. We show herein a relevant new effect regarding the orientation of side-chain mesogenic groups of LC polymers in a thin-film state. A subtle change in the main chain structure, i.e., polyacrylate and polymethacrylate, leads to a clear alternation of mesogens in the homeotropic and planar modes, respectively. This orientational discrimination is triggered from the free surface region (film-air interface) as revealed by surface micropatterning via inkjet printing
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|a Journal Article
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|a Nagashima, Yuki
|e verfasserin
|4 aut
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|a Hara, Mitsuo
|e verfasserin
|4 aut
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|a Nagano, Shusaku
|e verfasserin
|4 aut
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|a Seki, Takahiro
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 31(2015), 42 vom: 27. Okt., Seite 11379-83
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|x 1520-5827
|7 nnns
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|g volume:31
|g year:2015
|g number:42
|g day:27
|g month:10
|g pages:11379-83
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|u http://dx.doi.org/10.1021/acs.langmuir.5b02442
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