Substantial Difference in Ordering of 10, 15, and 20 nm Iron Oxide Nanoparticles on a Water Surface : In Situ Characterization by the Grazing Incidence X-ray Scattering
In the present study, for the first time, a unique combination of in situ grazing incidence small-angle X-ray scattering and X-ray reflectivity, accompanied by the pressure-area isotherm analysis, Brewster angle microscopy, and ex situ scanning electron microscopy, was applied for investigation of t...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1985. - 31(2015), 42 vom: 27. Okt., Seite 11639-48 |
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| Weitere Verfasser: | , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2015
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article |
| Zusammenfassung: | In the present study, for the first time, a unique combination of in situ grazing incidence small-angle X-ray scattering and X-ray reflectivity, accompanied by the pressure-area isotherm analysis, Brewster angle microscopy, and ex situ scanning electron microscopy, was applied for investigation of two-dimensional superlattices of magnetic nanoparticles as they form on a water surface in a Langmuir trough. Iron oxide particles of different sizes stabilized with a single layer of oleic acid were used. It is demonstrated that monodisperse 10 nm particles on a water surface reproducibly form identical highly ordered monolayers in a wide range of experimental conditions, while monodisperse 20 nm particles always form compact three-dimensional clusters and never the monolayers. Monodisperse particles of an intermediate size, 15 nm in diameter, build a metastable monolayer, which shows a tendency for spontaneous transformation to bi-, tri-, and multilayer islands. The importance to use both grazing incidence small-angle X-ray scattering and X-ray reflectivity together with the complementary techniques, to avoid misinterpretation of separate experimental data sets, is underlined |
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| Beschreibung: | Date Completed 14.03.2016 Date Revised 27.10.2015 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/acs.langmuir.5b02644 |