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231224s2016 xx |||||o 00| ||eng c |
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|a 10.1080/09593330.2015.1075601
|2 doi
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|a pubmed25n0842.xml
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|a (DE-627)NLM25274859X
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|a (NLM)26369315
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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|a Vemic, M
|e verfasserin
|4 aut
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|a Acid extraction of molybdenum, nickel and cobalt from mineral sludge generated by rainfall water at a metal recycling plant
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|c 2016
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
|b cr
|2 rdacarrier
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|a Date Completed 01.11.2016
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|a Date Revised 30.12.2016
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a This study investigated the leaching yields of Mo, Ni and Co from a mineral sludge of a metal recycling plant generated by rainfalls. The investigated mineral sludge had a complex heterogeneous composition, consisting of particles of settled soil combined with metal-bearing particles (produced by catalysts, metallic oxides and battery recycling). The leaching potential of different leaching reagents (stand-alone strong acids (HNO3 (68%), H2SO4 (98%) and HCl (36%)) and acid mixtures (aqua regia (nitric + hydrochloric (1:3)), nitric + sulphuric (1:1) and nitric + sulphuric + hydrochloric (2:1:1)) was investigated at changing operational parameters (solid-liquid (S/L) ratio, leaching time and temperature), in order to select the leaching reagent which achieves the highest metal leaching yields. Sulphuric acid (98% H2SO4) was found to be the leachant with the highest metal leaching potential. The optimal leaching conditions were a three-stage successive leaching at 80 °C with a leaching time of 2 h and S/L ratio of 0.25 g L(-1). Under these conditions, the achieved mineral sludge sample leaching yields were 85.5%, 40.5% and 93.8% for Mo, Ni and Co, respectively. The higher metal leaching potential of H2SO4 in comparison with the other strong acids/acid mixtures is attributed to the fact that H2SO4 is a diacidic compound, thus it has more H(+) ions, resulting in its stronger oxidizing power and corrosiveness
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a Mineral sludge
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|a chemical leaching
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|a leaching yields
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|a metals
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|a sulphuric acid
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|a Acids
|2 NLM
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|a Cobalt
|2 NLM
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|a 3G0H8C9362
|2 NLM
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|a Nickel
|2 NLM
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|a 7OV03QG267
|2 NLM
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|a Molybdenum
|2 NLM
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|a 81AH48963U
|2 NLM
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|a Bordas, F
|e verfasserin
|4 aut
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|a Guibaud, G
|e verfasserin
|4 aut
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|a Comte, S
|e verfasserin
|4 aut
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|a Joussein, E
|e verfasserin
|4 aut
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|a Lens, P N L
|e verfasserin
|4 aut
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|a Van Hullebusch, E D
|e verfasserin
|4 aut
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|i Enthalten in
|t Environmental technology
|d 1998
|g 37(2016), 5 vom: 29., Seite 630-9
|w (DE-627)NLM098202545
|x 1479-487X
|7 nnns
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|g volume:37
|g year:2016
|g number:5
|g day:29
|g pages:630-9
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|u http://dx.doi.org/10.1080/09593330.2015.1075601
|3 Volltext
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|d 37
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|e 5
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