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231224s2015 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.5b02829
|2 doi
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|a eng
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|a Gemmei-Ide, Makoto
|e verfasserin
|4 aut
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|a Mid-infrared spectroscopic investigation of the perfect vitrification of poly(ethylene glycol) aqueous solutions
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|c 2015
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|a Text
|b txt
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|a ƒaComputermedien
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|a ƒa Online-Ressource
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|a Date Completed 28.12.2015
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|a Date Revised 03.10.2015
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|a published: Print
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|a Citation Status PubMed-not-MEDLINE
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|a Crystallization/recrystallization behaviors of poly(ethylene glycol) (PEG) aqueous solutions with water contents (WC's) of ∼36-51 wt % were investigated by temperature-variable mid-infrared spectroscopy. At a WC of 43.2 wt %, crystallization and recrystallization of water and PEG were not observed. At this specific WC value (WCPV), perfect vitrification occurred. Below and above the WCPV value, crystallization/recrystallization behaviors changed drastically. The crystallization temperature below WCPV (237 K) was ∼10 K greater than that above WCPV (226 K). Recrystallization above and below WCPV occurred in one (213 K) and two (198 and 210 K) steps, respectively. These findings resulted from the difference in the (re)crystallization behaviors of water molecules associated with PEG chains with helical and random-coil conformations. These two types of water molecules might have limiting concentrations for their (re)crystallization, indicating that perfect vitrification might have occurred when the concentrations of the two types of water molecules were less than the limiting concentrations of their (re)crystallization
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|a Journal Article
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|a Miyashita, Takashi
|e verfasserin
|4 aut
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|a Kagaya, Shigehiro
|e verfasserin
|4 aut
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|a Kitano, Hiromi
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 31(2015), 39 vom: 06. Okt., Seite 10881-7
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|x 1520-5827
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|g volume:31
|g year:2015
|g number:39
|g day:06
|g month:10
|g pages:10881-7
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|u http://dx.doi.org/10.1021/acs.langmuir.5b02829
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