Observation of an Orientation Change in Highly Oriented Layer-by-Layer Films of a Ruthenium Complex upon Oxidation Reaction

Layer-by-layer films composed of redox-active ruthenium dimer and Zr(IV) ions were fabricated on an indium tin oxide electrode. The fabricating behavior was monitored by cyclic voltammetry and UV-vis absorption spectral measurements. The orientation of the film was also monitored by grazing-incidenc...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 31(2015), 38 vom: 29. Sept., Seite 10327-30
1. Verfasser: Kanaizuka, Katsuhiko (VerfasserIn)
Weitere Verfasser: Sasaki, Sono, Nakabayashi, Takuya, Masunaga, Hiroyasu, Ogawa, Hiroki, Hikima, Takaaki, Takata, Masaki, Haga, Masa-aki
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2015
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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245 1 0 |a Observation of an Orientation Change in Highly Oriented Layer-by-Layer Films of a Ruthenium Complex upon Oxidation Reaction 
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520 |a Layer-by-layer films composed of redox-active ruthenium dimer and Zr(IV) ions were fabricated on an indium tin oxide electrode. The fabricating behavior was monitored by cyclic voltammetry and UV-vis absorption spectral measurements. The orientation of the film was also monitored by grazing-incidence small-angle and wide-angle X-ray scattering (GISAXS) measurements, and it has been clarified that this film has a crystalline structure. The peaks obtained by GISAXS were changed upon oxidation reaction, which indicates that a change in the orientation of the ruthenium dimer occurred in the film 
650 4 |a Journal Article 
700 1 |a Sasaki, Sono  |e verfasserin  |4 aut 
700 1 |a Nakabayashi, Takuya  |e verfasserin  |4 aut 
700 1 |a Masunaga, Hiroyasu  |e verfasserin  |4 aut 
700 1 |a Ogawa, Hiroki  |e verfasserin  |4 aut 
700 1 |a Hikima, Takaaki  |e verfasserin  |4 aut 
700 1 |a Takata, Masaki  |e verfasserin  |4 aut 
700 1 |a Haga, Masa-aki  |e verfasserin  |4 aut 
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