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231224s2015 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.5b02838
|2 doi
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|a pubmed24n0841.xml
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|a (DE-627)NLM252420896
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|a DE-627
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|e rakwb
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|a eng
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| 100 |
1 |
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|a da Silva, Anderson G M
|e verfasserin
|4 aut
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| 245 |
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|a The Fault in Their Shapes
|b Investigating the Surface-Plasmon-Resonance-Mediated Catalytic Activities of Silver Quasi-Spheres, Cubes, Triangular Prisms, and Wires
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|c 2015
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Completed 07.12.2015
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|a Date Revised 22.09.2015
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a The surface-plasmon-resonance (SPR)-mediated catalytic activities of Ag and Au nanoparticles have emerged a relatively new frontier in catalysis in which visible light can be employed as an eco-friendly energy input to drive chemical reactions. Although this phenomenon has been reported for a variety of transformations, the effect of the nanoparticle shape and crystalline structure on the activities remains unclear. In this paper, we investigated the SPR-mediated catalytic activity of Ag quasi-spheres, cubes, triangular prisms, and wires toward the oxidation of p-aminothiophenol to p,p'-dimercaptoazobenzene by activated O2. The activities at 632.8 nm excitation followed the order triangular prisms and quasi-spheres > wires ≫ cubes. These results indicated that the shape, optical properties, and crystal structure played an important role in the detected SPR-mediated activities
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|a Journal Article
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|a Rodrigues, Thenner S
|e verfasserin
|4 aut
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| 700 |
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|a Wang, Jiale
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Yamada, Liliam K
|e verfasserin
|4 aut
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| 700 |
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|a Alves, Tiago V
|e verfasserin
|4 aut
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| 700 |
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|a Ornellas, Fernando R
|e verfasserin
|4 aut
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|a Ando, Rômulo A
|e verfasserin
|4 aut
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| 700 |
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|a Camargo, Pedro H C
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 31(2015), 37 vom: 22. Sept., Seite 10272-8
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
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|g volume:31
|g year:2015
|g number:37
|g day:22
|g month:09
|g pages:10272-8
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|u http://dx.doi.org/10.1021/acs.langmuir.5b02838
|3 Volltext
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