A nitrogen and sulfur dual-doped carbon derived from polyrhodanine@cellulose for advanced lithium-sulfur batteries

A nitrogen and sulfur dual-doped carbon derived from polyrhodanine@cellulose for advanced lithium-sulfur batteries

© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 27(2015), 39 vom: 21. Okt., Seite 6021-8
1. Verfasser: Pang, Quan (VerfasserIn)
Weitere Verfasser: Tang, Juntao, Huang, He, Liang, Xiao, Hart, Connor, Tam, Kam C, Nazar, Linda F
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2015
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article biosustainable materials chemisorptions dual-doped carbon lithium-sulfur batteries polysulfide binding
Beschreibung
Zusammenfassung:© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
A sulfur electrode exhibiting strong polysulfide chemisorption using a porous N, S dual-doped carbon is reported. The synergistic functionalization from the N and S heteroatoms dramatically modifies the electron density distribution and leads to much stronger polysulfide binding. X-ray photoelectron spectroscopy studies combined with ab initio calculations reveal strong Li(+) -N and Sn (2-) -S interactions. The sulfur electrodes exhibit an ultralow capacity fading of 0.052% per cycle over 1100 cycles
Beschreibung:Date Completed 13.01.2016
Date Revised 01.10.2020
published: Print-Electronic
Citation Status PubMed-not-MEDLINE
ISSN:1521-4095
DOI:10.1002/adma.201502467