Simultaneous column preconcentration of ultra trace amounts of heavy metals with nano-adsorbent in some environmental and biological samples

In the present investigation, multi-walled carbon nanotubes impregnated by 1,4,10,13-tetraoxa-7,16-diazacyclooctadecane were prepared and applied as adsorbent for the simultaneous separation of Bi(III), Cu(II), Cd(II) and Pb(II) ions prior to their determination by electrothermal atomic absorption s...

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Détails bibliographiques
Publié dans:Environmental technology. - 1998. - 37(2016), 3 vom: 01., Seite 300-7
Auteur principal: Fazelirad, Hamid (Auteur)
Autres auteurs: Taher, Mohammad Ali
Format: Article en ligne
Langue:English
Publié: 2016
Accès à la collection:Environmental technology
Sujets:Journal Article bismuth cadmium copper lead multi-walled carbon nanotubes Crown Ethers Metals, Heavy Nanotubes, Carbon Water Pollutants, Chemical plus... cryptand 2.2 23978-55-4
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520 |a In the present investigation, multi-walled carbon nanotubes impregnated by 1,4,10,13-tetraoxa-7,16-diazacyclooctadecane were prepared and applied as adsorbent for the simultaneous separation of Bi(III), Cu(II), Cd(II) and Pb(II) ions prior to their determination by electrothermal atomic absorption spectrometry. The following analytical figures of merit were determined for bismuth, copper, cadmium and lead, respectively: enrichment factors of 168, 134, 111 and 146, assay precisions of ±4.6%, ±4.8%, ±5.3% and ±5.0% and detection limits of 11.3, 3.7, 0.5 and 0.3 ng L(-1). The method was successfully applied for the determination of heavy metals in environmental, biological and certified reference materials 
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