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231224s2015 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.5b01497
|2 doi
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|a pubmed24n0835.xml
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|a eng
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1 |
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|a Murialdo, Maxwell
|e verfasserin
|4 aut
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| 245 |
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|a Krypton Adsorption on Zeolite-Templated Carbon and Anomalous Surface Thermodynamics
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|c 2015
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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| 338 |
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|a ƒa Online-Ressource
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|2 rdacarrier
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| 500 |
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|a Date Completed 02.10.2015
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|a Date Revised 28.07.2015
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Krypton adsorption was measured at eight temperatures between 253 and 433 K on a zeolite-templated carbon and two commercial carbons. The data were fitted using a generalized Langmuir isotherm model and thermodynamic properties were extracted. Differing from that on commercial carbons, krypton adsorption on the zeolite-templated carbon is accompanied by an increasing isosteric enthalpy of adsorption, rising by up to 1.4 kJ mol(-1) as a function of coverage. This increase is a result of enhanced adsorbate-adsorbate interactions promoted by the ordered, nanostructured surface of the adsorbent. An assessment of the strength and nature of these adsorbate-adsorbate interactions is made by comparing the measured isosteric enthalpies of adsorption (and other thermodynamic quantities) to fundamental metrics of intermolecular interactions of krypton and other common gases
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|a Journal Article
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|a Stadie, Nicholas P
|e verfasserin
|4 aut
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1 |
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|a Ahn, Channing C
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Fultz, Brent
|e verfasserin
|4 aut
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| 773 |
0 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 31(2015), 29 vom: 28. Juli, Seite 7991-8
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
1 |
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|g volume:31
|g year:2015
|g number:29
|g day:28
|g month:07
|g pages:7991-8
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|u http://dx.doi.org/10.1021/acs.langmuir.5b01497
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