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231224s2015 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.5b01383
|2 doi
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|a pubmed24n0832.xml
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|a DE-627
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|a eng
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|a Bhandari, Rohit
|e verfasserin
|4 aut
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|a Electrochemical Activity of Dendrimer-Stabilized Tin Nanoparticles for Lithium Alloying Reactions
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|c 2015
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|a Text
|b txt
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|a ƒaComputermedien
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|a ƒa Online-Ressource
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|a Date Completed 14.08.2015
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|a Date Revised 16.06.2015
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a The synthesis and characterization of Sn nanoparticles in organic solvents using sixth-generation dendrimers modified on their periphery with hydrophobic groups as stabilizers are reported. Sn(2+):dendrimer ratios of 147 and 225 were employed for the synthesis, corresponding to formation of Sn147 and Sn225 dendrimer-stabilized nanoparticles (DSNs). Transmission electron microscopy analysis indicated the presence of ultrasmall Sn nanoparticles having an average size of 3.0-5.0 nm. X-ray absorption spectroscopy suggested the presence of Sn nanoparticles with only partially oxidized surfaces. Cyclic voltammetry studies of the Sn DSNs for Li alloying/dealloying reactions demonstrated good reversibility. Control experiments carried out in the absence of DSNs clearly indicated that these ultrasmall Sn DSNs react directly with Li to form SnLi alloys
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|a Journal Article
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|a Anderson, Rachel M
|e verfasserin
|4 aut
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|a Stauffer, Shannon
|e verfasserin
|4 aut
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|a Dylla, Anthony G
|e verfasserin
|4 aut
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|a Henkelman, Graeme
|e verfasserin
|4 aut
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|a Stevenson, Keith J
|e verfasserin
|4 aut
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|a Crooks, Richard M
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 31(2015), 23 vom: 16. Juni, Seite 6570-6
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
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|g volume:31
|g year:2015
|g number:23
|g day:16
|g month:06
|g pages:6570-6
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|u http://dx.doi.org/10.1021/acs.langmuir.5b01383
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