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231224s2015 xx |||||o 00| ||eng c |
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|a 10.2166/wst.2015.149
|2 doi
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|a pubmed25n0832.xml
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|a (NLM)26038933
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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1 |
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|a Hu, Xuefeng
|e verfasserin
|4 aut
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|a Aniline chlorination by in situ formed Ag-Cl complexes under simulated solar light irradiation
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|c 2015
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Completed 06.10.2015
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|a Date Revised 02.12.2018
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|a published: Print
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|a Citation Status MEDLINE
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|a Ag speciation in a chloride medium was dependent upon the Cl/Ag ratio after releasing into surface water. In this study, the photoreaction of in situ formed Ag-Cl species and their effects on aniline photochlorination were systematically investigated. Our results suggested that formation of chloroaniline was strongly relevant to the Cl/Ag ratio and could be interpreted using the thermodynamically expected speciation of Ag in the presence of Cl-. AgCl was the main species responsible for the photochlorination of aniline. Both photoinduced hole and •OH drove the oxidation of Cl- to radical •Cl, which promoted the chlorination of aniline. Ag0 formation was observed from the surface plasmon resonance absorption during AgCl photoreaction. This study revealed that Ag+ released into Cl--containing water may result in the formation of chlorinated intermediates of organic compounds under solar light irradiation
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a Aniline Compounds
|2 NLM
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|a Chlorides
|2 NLM
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| 650 |
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|a Water Pollutants, Chemical
|2 NLM
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|a Silver
|2 NLM
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| 650 |
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|a 3M4G523W1G
|2 NLM
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|a aniline
|2 NLM
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|a SIR7XX2F1K
|2 NLM
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|a Wang, Xiaowen
|e verfasserin
|4 aut
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1 |
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|a Dong, Liuliu
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Chang, Fei
|e verfasserin
|4 aut
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1 |
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|a Luo, Yongming
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Water science and technology : a journal of the International Association on Water Pollution Research
|d 1986
|g 71(2015), 11 vom: 07., Seite 1679-85
|w (DE-627)NLM098149431
|x 1996-9732
|7 nnns
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| 773 |
1 |
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|g volume:71
|g year:2015
|g number:11
|g day:07
|g pages:1679-85
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|u http://dx.doi.org/10.2166/wst.2015.149
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