Identifying the Structure of the Intermediate, Li2/3CoPO4, Formed during Electrochemical Cycling of LiCoPO4

In situ synchrotron diffraction measurements and subsequent Rietveld refinements are used to show that the high energy density cathode material LiCoPO4 (space group Pnma) undergoes two distinct two-phase reactions upon charge and discharge, both occurring via an intermediate Li2/3(Co2+)2/3(Co3+)1/3P...

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Veröffentlicht in:	Chemistry of materials : a publication of the American Chemical Society. - 1998. - 26(2014), 21 vom: 11. Nov., Seite 6193-6205
1. Verfasser:	Strobridge, Fiona C (VerfasserIn)
Weitere Verfasser:	Clément, Raphaële J, Leskes, Michal, Middlemiss, Derek S, Borkiewicz, Olaf J, Wiaderek, Kamila M, Chapman, Karena W, Chupas, Peter J, Grey, Clare P
Format:	Aufsatz
Sprache:	English
Veröffentlicht:	2014
Zugriff auf das übergeordnete Werk:	Chemistry of materials : a publication of the American Chemical Society
Schlagworte:	Journal Article