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|a DE-627
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|e rakwb
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|a eng
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| 100 |
1 |
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|a Zitz, Rainer
|e verfasserin
|4 aut
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| 245 |
1 |
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|a Oligosilanylated Antimony Compounds
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| 264 |
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|c 2015
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| 336 |
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|a Text
|b txt
|2 rdacontent
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|a ohne Hilfsmittel zu benutzen
|b n
|2 rdamedia
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| 338 |
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|a Band
|b nc
|2 rdacarrier
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| 500 |
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|a Date Revised 22.03.2024
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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| 520 |
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|a By reactions of magnesium oligosilanides with SbCl3, a number of oligosilanylated antimony compounds were obtained. When oligosilanyl dianions were used, either the expected cyclic disilylated halostibine was obtained or alternatively the formation of a distibine was observed. Deliberate formation of the distibine from the disilylated halostibine was achieved by reductive coupling with C8K. Computational studies of Sb-Sb bond energies, barriers of pyramidal inversion at Sb, and the conformational behavior of distibines provided insight for the understanding of the spectroscopic properties
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| 650 |
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|a Journal Article
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1 |
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|a Gatterer, Karl
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Reinhold, Crispin R W
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Müller, Thomas
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Baumgartner, Judith
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Marschner, Christoph
|e verfasserin
|4 aut
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| 773 |
0 |
8 |
|i Enthalten in
|t Organometallics
|d 1998
|g 34(2015), 8 vom: 27. Apr., Seite 1419-1430
|w (DE-627)NLM098167103
|x 0276-7333
|7 nnas
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| 773 |
1 |
8 |
|g volume:34
|g year:2015
|g number:8
|g day:27
|g month:04
|g pages:1419-1430
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|a AR
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| 952 |
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|d 34
|j 2015
|e 8
|b 27
|c 04
|h 1419-1430
|