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231224s2015 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.5b00235
|2 doi
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|a pubmed24n0827.xml
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|a eng
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|a Guterman, Ryan
|e verfasserin
|4 aut
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|a Kinetically controlled patterning of highly cross-linked phosphonium photopolymers using simple anion exchange
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|c 2015
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Completed 04.02.2016
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|a Date Revised 12.05.2015
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a A phosphonium salt possessing three methacrylate groups has been incorporated into a photopolymeric system to generate highly cross-linked polyelectrolyte networks. Emergent chemical and physical properties in the polymers were observed and attributed to the tandem increase in cross-link density and ion-content upon incorporation of the self-cross-linking cation. Anion-exchange with bis(trifluoromethylsulfonyl)imide or dodecylbenzenesulfonate resulted in significant differences in wettability and ion-exchange behavior. The passivating effects of dodecylbenzenesulfonate were utilized to selectively pattern fluorescein dye into the polymer network, highlighting a new patterning procedure using ionic-bond forming reactions
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a Anions
|2 NLM
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|a Polymers
|2 NLM
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|a Gillies, Elizabeth R
|e verfasserin
|4 aut
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|a Ragogna, Paul J
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 31(2015), 18 vom: 12. Mai, Seite 5181-9
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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| 773 |
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|g volume:31
|g year:2015
|g number:18
|g day:12
|g month:05
|g pages:5181-9
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|u http://dx.doi.org/10.1021/acs.langmuir.5b00235
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