|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM24810795X |
| 003 |
DE-627 |
| 005 |
20231224150703.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231224s2015 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1021/acs.langmuir.5b00817
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n0827.xml
|
| 035 |
|
|
|a (DE-627)NLM24810795X
|
| 035 |
|
|
|a (NLM)25879684
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a de Molina, Paula Malo
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Phase Behavior of Nonionic Microemulsions with Multi-end-capped Polymers and Its Relation to the Mesoscopic Structure
|
| 264 |
|
1 |
|c 2015
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Completed 08.07.2015
|
| 500 |
|
|
|a Date Revised 12.05.2015
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a The polymer architecture of telechelic or associative polymers has a large impact on the bridging of self-assembled structures. This work presents the phase behavior, small angle neutron scattering (SANS), dynamic light scattering (DLS), and fluorescence correlation spectroscopy (FCS) of a nonionic oil-in-water (O/W) microemulsion with hydrophobically end-capped multiarm polymers with functionalities f = 2, 3, and 4. For high polymer concentrations and large average interdroplet distance relative to the end-to-end distance of the polymer, d/R(ee), the system phase separates into a dense, highly connected droplet network phase, in equilibrium with a dilute phase. The extent of the two-phase region is larger for polymers with similar length but higher f. The interaction potential between the droplets in the presence of polymer has both a repulsive and an attractive contribution as a result of the counterbalancing effects of the exclusion by polymer chains and bridging between droplets. This study experimentally demonstrates that higher polymer functionalities induce a stronger attractive force between droplets, which is responsible for a more extended phase separation region, and correlate with lower collective droplet diffusivities and higher amplitude of the second relaxation time in DLS. The viscosity and the droplet self-diffusion obtained from FCS, however, are dominated by the end-capped chain concentration
|
| 650 |
|
4 |
|a Journal Article
|
| 700 |
1 |
|
|a Ihlefeldt, Franziska Stefanie
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Prévost, Sylvain
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Herfurth, Christoph
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Appavou, Marie-Sousai
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Laschewsky, André
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Gradzielski, Michael
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 31(2015), 18 vom: 12. Mai, Seite 5198-209
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
|
| 773 |
1 |
8 |
|g volume:31
|g year:2015
|g number:18
|g day:12
|g month:05
|g pages:5198-209
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1021/acs.langmuir.5b00817
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_22
|
| 912 |
|
|
|a GBV_ILN_350
|
| 912 |
|
|
|a GBV_ILN_721
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 31
|j 2015
|e 18
|b 12
|c 05
|h 5198-209
|