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231224s2015 xx |||||o 00| ||eng c |
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|a 10.1002/adma.201405623
|2 doi
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|a pubmed24n0823.xml
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|a DE-627
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|a eng
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|a Ward, Alexander J
|e verfasserin
|4 aut
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|a The impact of driving force on electron transfer rates in photovoltaic donor-acceptor blends
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|c 2015
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Completed 05.06.2015
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|a Date Revised 01.10.2020
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2015 The Authors. Published by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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|a The effect of acceptor energy level on electron transfer rate in blends of the polymer solar-cell material poly[[4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b']dithiophene-2,6-diyl][3-fluoro-2-[(2-ethylhexyl)carbonyl]thieno[3,4-b]thiophenediyl]] (PTB7) is studied using time-resolved fluorescence. Fast electron transfer in less than 2 ps is observed for a driving force between 0.2 and 0.6 eV and the electron transfer is slower outside this range. This dependence is described by Marcus theory with a reorganization energy of ≈0.4 eV
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|a Journal Article
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|a PTB7
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|a charge generation
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|a excitonic solar cells
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|a reorganization energy
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|a Ruseckas, Arvydas
|e verfasserin
|4 aut
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|a Kareem, Mohanad Mousa
|e verfasserin
|4 aut
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|a Ebenhoch, Bernd
|e verfasserin
|4 aut
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|a Serrano, Luis A
|e verfasserin
|4 aut
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|a Al-Eid, Manal
|e verfasserin
|4 aut
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1 |
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|a Fitzpatrick, Brian
|e verfasserin
|4 aut
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|a Rotello, Vincent M
|e verfasserin
|4 aut
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|a Cooke, Graeme
|e verfasserin
|4 aut
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|a Samuel, Ifor D W
|e verfasserin
|4 aut
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 27(2015), 15 vom: 17. Apr., Seite 2496-500
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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|g volume:27
|g year:2015
|g number:15
|g day:17
|g month:04
|g pages:2496-500
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|u http://dx.doi.org/10.1002/adma.201405623
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