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231224s2015 xx |||||o 00| ||eng c |
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|a 10.1021/la504447t
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|a eng
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| 100 |
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|a Alonso, Jose Maria
|e verfasserin
|4 aut
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| 245 |
1 |
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|a Covalent attachment of 1-alkenes to oxidized platinum surfaces
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|c 2015
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|a Text
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|a ƒaComputermedien
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|a Date Completed 11.05.2015
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|a Date Revised 10.03.2015
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a We report the formation of covalently bound alkyl layers onto oxidized Pt (PtOx) substrates by reaction with 1-alkenes as a novel way to bind organic molecules to metal surfaces. The organic layers were characterized by static contact angle, infrared reflection absorption spectroscopy (IRRAS), X-ray photoelectron spectroscopy (XPS), and atomic force microscopy (AFM). The grafted alkyl layers display a hydrolytic stability that is comparable to that of alkyl thiols on Au. PtOx-alkene attachment is compatible with terminal ester moieties enabling further anchoring of functional groups, such as redox-active ferrocene, and thus has great potential to extend monolayer chemistry on noble metals
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|a Journal Article
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| 700 |
1 |
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|a Fabre, Bruno
|e verfasserin
|4 aut
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| 700 |
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|a Trilling, Anke K
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Scheres, Luc
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Franssen, Maurice C R
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Zuilhof, Han
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 31(2015), 9 vom: 10. März, Seite 2714-21
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|g month:03
|g pages:2714-21
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