Ultrafast charge transfer in operating bulk heterojunction solar cells
© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Publié dans: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 27(2015), 12 vom: 25. März, Seite 2036-41 |
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Auteur principal: | |
Autres auteurs: | , , , , , , |
Format: | Article en ligne |
Langue: | English |
Publié: |
2015
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Accès à la collection: | Advanced materials (Deerfield Beach, Fla.) |
Sujets: | Journal Article bulk heterojunctions organic solar cells transient reflection spectroscopy ultrafast charge transfer |
Résumé: | © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. The ultrafast charge generation process in organic solar cell devices is investigated by transient reflection spectroscopy on five state-of-the-art bulk heterojunction systems. The charge generation process in operating devices is found to be a combination of an ultrafast generation mechanism over several hundred femto-seconds and a slow process from pico-seconds to nanoseconds, limited by exciton diffusion dynamics. In addition, the lack of electric field dependence in the charge dynamics rules out geminate recombination as an important loss mechanism |
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Description: | Date Completed 15.05.2015 Date Revised 30.09.2020 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
ISSN: | 1521-4095 |
DOI: | 10.1002/adma.201405284 |