|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM246017236 |
| 003 |
DE-627 |
| 005 |
20231224142144.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231224s2015 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1021/la5044798
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n0820.xml
|
| 035 |
|
|
|a (DE-627)NLM246017236
|
| 035 |
|
|
|a (NLM)25658859
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Theodorakis, Panagiotis E
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Superspreading
|b mechanisms and molecular design
|
| 264 |
|
1 |
|c 2015
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Completed 21.05.2015
|
| 500 |
|
|
|a Date Revised 03.03.2015
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a The intriguing ability of certain surfactant molecules to drive the superspreading of liquids to complete wetting on hydrophobic substrates is central to numerous applications that range from coating flow technology to enhanced oil recovery. Despite significant experimental efforts, the precise mechanisms underlying superspreading remain unknown to date. Here, we isolate these mechanisms by analyzing coarse-grained molecular dynamics simulations of surfactant molecules of varying molecular architecture and substrate affinity. We observe that for superspreading to occur, two key conditions must be simultaneously satisfied: the adsorption of surfactants from the liquid-vapor surface onto the three-phase contact line augmented by local bilayer formation. Crucially, this must be coordinated with the rapid replenishment of liquid-vapor and solid-liquid interfaces with surfactants from the interior of the droplet. This article also highlights and explores the differences between superspreading and conventional surfactants, paving the way for the design of molecular architectures tailored specifically for applications that rely on the control of wetting
|
| 650 |
|
4 |
|a Journal Article
|
| 700 |
1 |
|
|a Müller, Erich A
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Craster, Richard V
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Matar, Omar K
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 31(2015), 8 vom: 03. März, Seite 2304-9
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
|
| 773 |
1 |
8 |
|g volume:31
|g year:2015
|g number:8
|g day:03
|g month:03
|g pages:2304-9
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1021/la5044798
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_22
|
| 912 |
|
|
|a GBV_ILN_350
|
| 912 |
|
|
|a GBV_ILN_721
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 31
|j 2015
|e 8
|b 03
|c 03
|h 2304-9
|