Mineralogy and metals speciation in Mo rich mineral sludges generated at a metal recycling plant

Copyright © 2015 Elsevier Ltd. All rights reserved.

Bibliographische Detailangaben
Veröffentlicht in:Waste management (New York, N.Y.). - 1999. - 38(2015) vom: 27. Apr., Seite 303-11
1. Verfasser: Vemic, M (VerfasserIn)
Weitere Verfasser: Bordas, F, Guibaud, G, Joussein, E, Labanowski, J, Lens, P N L, van Hullebusch, E D
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2015
Zugriff auf das übergeordnete Werk:Waste management (New York, N.Y.)
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Characterization Industrial mineral sludge Leaching characteristics Metals TCLP Metals, Heavy Sewage Molybdenum 81AH48963U
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520 |a In France, more than 250 million metric tons of sludges need to be treated each year. These sludges are either dumped on the landfills or reused as secondary resources in order to preserve natural resources. A large portions of these sludges are mineral sludges, originating from metal recycling plants. In order to estimate their metal recovery potential, these mineral sludges were characterized. Four types of mineral sludge samples were collected from a metal recycling plant (3 from the recycling plant storage areas (bulk storage, barrel storage and storage shed) and 1 from the collection basin). The sludges were characterized, wherein the Mo, Ni, Cr, Co, Zn and W content and speciation were quantified. The samples had pH values between 5.9 and 10.3 with organic matter contents varying between 6.3% (storage shed) and 29.5% (bulk storage) (loss on ignition at 500 °C). Based on their leaching properties, the four mineral sludge samples (in the case of Mo) and the bulk storage sludge (in the case of Ni and Zn) were classified as potentially hazardous regarding the EN 12457-1 and EN 12457-2 method. Mineralogical results reveal that both bulk storage and the storage shed give the highest contributions to the metal content of the collection basin sample. Sequential extraction of the collection basin samples indicated that Mo is bound to the oxidizable and residual fraction, while Ni, Cr and Co were bound to the residual fraction, and Zn to the soluble acid fraction, respectively. W tends to be equally distributed among all extracted fractions. A strong correlation existed between Mo and Co, as well as between Ni, Zn and Cr, respectively 
650 4 |a Journal Article 
650 4 |a Research Support, Non-U.S. Gov't 
650 4 |a Characterization 
650 4 |a Industrial mineral sludge 
650 4 |a Leaching characteristics 
650 4 |a Metals 
650 4 |a TCLP 
650 7 |a Metals, Heavy  |2 NLM 
650 7 |a Sewage  |2 NLM 
650 7 |a Molybdenum  |2 NLM 
650 7 |a 81AH48963U  |2 NLM 
700 1 |a Bordas, F  |e verfasserin  |4 aut 
700 1 |a Guibaud, G  |e verfasserin  |4 aut 
700 1 |a Joussein, E  |e verfasserin  |4 aut 
700 1 |a Labanowski, J  |e verfasserin  |4 aut 
700 1 |a Lens, P N L  |e verfasserin  |4 aut 
700 1 |a van Hullebusch, E D  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Waste management (New York, N.Y.)  |d 1999  |g 38(2015) vom: 27. Apr., Seite 303-11  |w (DE-627)NLM098197061  |x 1879-2456  |7 nnns 
773 1 8 |g volume:38  |g year:2015  |g day:27  |g month:04  |g pages:303-11 
856 4 0 |u http://dx.doi.org/10.1016/j.wasman.2014.12.021  |3 Volltext 
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