Kinetics and mechanism of the reaction of hydrogen sulfide with diaquacobinamide in aqueous solution
We conducted a detailed kinetic study of the reaction of the vitamin B12 analog diaquacobinamide ((H2O)2Cbi(III)) with hydrogen sulfide in water from pH 3 to 11. The reaction proceeds in three steps: (i) formation of three different complexes between cobinamide and hydrogen sulfide, viz. (HO-)(HS-)C...
| Veröffentlicht in: | European journal of inorganic chemistry. - 1998. - 2014(2014), 25 vom: 24. Sept., Seite 4123-4133 |
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| Format: | Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2014
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| Zugriff auf das übergeordnete Werk: | European journal of inorganic chemistry |
| Schlagworte: | Journal Article Cobinamide Hydrogen sulfide Kinetics Reaction mechanisms Redox chemistry |