Extended X-ray absorption fine structure and multiple-scattering simulation of nickel dithiolene complexes Ni[S2C2(CF3)2]2(n) (n = -2, -1, 0) and an olefin adduct Ni[S2C2(CF3)2]2(1-hexene)
A series of Ni dithiolene complexes Ni[S2C2(CF3)]2(n) (n = -2, -1, 0) (1, 2, 3) and a 1-hexene adduct Ni[S2C2(CF3)2]2(C6H12) (4) have been examined by Ni K-edge X-ray absorption near-edge structure (XANES) and extended X-ray absorption fine-structure (EXAFS) spectroscopies. Ni XANES for 1-3 reveals...
Description complète