Protecting metal-organic framework crystals from hydrolytic degradation by spray-dry encapsulating them into polystyrene microspheres

Protecting metal-organic framework crystals from hydrolytic degradation by spray-dry encapsulating them into polystyrene microspheres

© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 27(2015), 5 vom: 04. Feb., Seite 869-73
1. Verfasser: Carné-Sánchez, Arnau (VerfasserIn)
Weitere Verfasser: Stylianou, Kyriakos C, Carbonell, Carlos, Naderi, Majid, Imaz, Inhar, Maspoch, Daniel
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2015
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article composites metal-organic frameworks organic polymers spray-drying synthesis water sorption
Beschreibung
Zusammenfassung:© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Many metal-organic frameworks are water labile, including the iconic Hong-Kong University of Science and Technology-1 (HKUST-1). Spray-dry encapsulation of HKUST-1 crystals into polystyrene microspheres is reported here to yield composites that are resistant to water but retain most of the excellent gas sorption capacity of HKUST-1. These composites are demonstrated to exhibit superior water adsorption/desorption cycling, maintaining the level of water uptake even after three cycles
Beschreibung:Date Completed 19.05.2015
Date Revised 29.01.2022
published: Print-Electronic
Citation Status PubMed-not-MEDLINE
ISSN:1521-4095
DOI:10.1002/adma.201403827