Facile synthesis of AuPt alloy nanoparticles in polyelectrolyte multilayers with enhanced catalytic activity for reduction of 4-nitrophenol

In this work, bimetallic AuPt alloy nanoparticles were synthesized in situ in polyelectrolyte multilayers (PEMs) via an ion-exchange and coreduction process, in which the PEM support also served to suppress the Au-Pt phase separation, and thus enabled formation of AuPt alloy nanoparticles over a wid...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 30(2014), 50 vom: 23. Dez., Seite 15345-50
1. Verfasser: Chu, Chengcan (VerfasserIn)
Weitere Verfasser: Su, Zhaohui
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2014
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a In this work, bimetallic AuPt alloy nanoparticles were synthesized in situ in polyelectrolyte multilayers (PEMs) via an ion-exchange and coreduction process, in which the PEM support also served to suppress the Au-Pt phase separation, and thus enabled formation of AuPt alloy nanoparticles over a wide composition range. The PEM supported AuPt alloy nanoparticles exhibited higher catalytic activity than Au and Pt monometallic ones for the reduction of 4-nitrophenol by NaBH4, showing synergistic effects between Au and Pt. This work provides a facile approach to in situ synthesis of polymer supported bimetallic nanoparticles of tailored composition for optimum performance in catalysis and other applications 
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