|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM244079994 |
| 003 |
DE-627 |
| 005 |
20231224133924.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
231224s2014 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1021/la5039798
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n0813.xml
|
| 035 |
|
|
|a (DE-627)NLM244079994
|
| 035 |
|
|
|a (NLM)25453500
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Cao, Jianhua
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Ternary system based on fluorophore-surfactant assemblies--Cu²⁺ for highly sensitive and selective detection of arginine in aqueous solution
|
| 264 |
|
1 |
|c 2014
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Completed 13.08.2015
|
| 500 |
|
|
|a Date Revised 23.12.2014
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status MEDLINE
|
| 520 |
|
|
|a A new cationic dansyl derivative-based (DIlSD) fluorescence probe was designed and synthesized. Its combination with anionic surfactant SDS assemblies shows enhanced fluorescence intensity and blue-shifted maximum wavelength. Its fluorescence can be slightly quenched by Cu(2+); however, the fluorescence quenching efficiency by Cu(2+) is highly increased upon titration of arginine (Arg). As a result, the ternary system containing the cationic fluorophore, anionic surfactant, and Cu(2+) functions as a highly sensitive and selective sensor to Arg. The optimized sensor system displays a detection limit of 170 nM, representing the highest sensitivity to Arg in total aqueous solution by a fluorescent sensor. Control experiments reveal that the imidazolium groups in the fluorophore, the anionic surfactant, and Cu(2+) all play important roles in the process of sensing Arg. The electrostatic interaction between the cationic fluorophore and anionic surfactants facilitates the binding of imidazolium rings with Cu(2+), the surfactant surface-anchored Cu(2+) is responsible for further binding of Arg, and the electrostatic interaction between anionic surfactants and positively charged amino acids accounts for the selective responses to Arg
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a Research Support, Non-U.S. Gov't
|
| 650 |
|
7 |
|a Dansyl Compounds
|2 NLM
|
| 650 |
|
7 |
|a Fluorescent Dyes
|2 NLM
|
| 650 |
|
7 |
|a Imidazoles
|2 NLM
|
| 650 |
|
7 |
|a Solutions
|2 NLM
|
| 650 |
|
7 |
|a Surface-Active Agents
|2 NLM
|
| 650 |
|
7 |
|a Water
|2 NLM
|
| 650 |
|
7 |
|a 059QF0KO0R
|2 NLM
|
| 650 |
|
7 |
|a Sodium Dodecyl Sulfate
|2 NLM
|
| 650 |
|
7 |
|a 368GB5141J
|2 NLM
|
| 650 |
|
7 |
|a Copper
|2 NLM
|
| 650 |
|
7 |
|a 789U1901C5
|2 NLM
|
| 650 |
|
7 |
|a imidazole
|2 NLM
|
| 650 |
|
7 |
|a 7GBN705NH1
|2 NLM
|
| 650 |
|
7 |
|a Arginine
|2 NLM
|
| 650 |
|
7 |
|a 94ZLA3W45F
|2 NLM
|
| 700 |
1 |
|
|a Ding, Liping
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Hu, Wenting
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Chen, Xiangli
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Chen, Xiao
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Fang, Yu
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 30(2014), 50 vom: 23. Dez., Seite 15364-72
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
|
| 773 |
1 |
8 |
|g volume:30
|g year:2014
|g number:50
|g day:23
|g month:12
|g pages:15364-72
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1021/la5039798
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_22
|
| 912 |
|
|
|a GBV_ILN_350
|
| 912 |
|
|
|a GBV_ILN_721
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 30
|j 2014
|e 50
|b 23
|c 12
|h 15364-72
|