Evidence for interaction with the water subphase as the origin and stabilization of nano-domain in semi-fluorinated alkanes monolayer at the air/water interface
Multilayer films of semifluorinated alkanes (SFAs) at the air/water interface were studied in situ by grazing incidence small-angle X-ray scattering (GISAXS). The results provide evidence that the first layer in contact with the water subphase, buried below the overlayers, exhibits the same supramol...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1992. - 30(2014), 50 vom: 23. Dez., Seite 15193-9 |
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| Weitere Verfasser: | , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2014
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article |
| Zusammenfassung: | Multilayer films of semifluorinated alkanes (SFAs) at the air/water interface were studied in situ by grazing incidence small-angle X-ray scattering (GISAXS). The results provide evidence that the first layer in contact with the water subphase, buried below the overlayers, exhibits the same supramolecular hexagonal structure that is observed in the monolayer before the collapse, at non-zero surface pressure. We believe this result clearly demonstrates the major role of the interactions between the first layer of SFAs and the water subphase to the formation of the structure |
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| Beschreibung: | Date Completed 19.05.2015 Date Revised 23.12.2014 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/la5038124 |